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  1. In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters.

  2. These rules are additions and extensions to Wade's rules and polyhedral skeletal electron pair theory. The Jemmis mno rule provides the relationship between polyhedral boranes, condensed polyhedral boranes, and β-rhombohedral boron.

  3. 6 de jul. de 2020 · It is widely known that the skeletal structure of clusters reflects the number of skeletal bonding electron pairs involved, which is called the polyhedral skeletal electron pair theory (PSEPT) or...

    • Wei Lu, Dinh Cao Huan Do, Rei Kinjo
    • 2020
  4. In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters.

  5. In chemistry the polyhedral skeletal electron pair theory provides electron counting rules used to predict the structure of electron deficient clusters. They were originally formulated by K. Wade and further developed by Mingos and others, and are sometimes known as Wade's Rules or Wade / Mingos rules.

  6. This chapter explores the polyhedral skeletal electron pair theory (PSEPT), which relates the three-dimensional structures of polyhedral molecules to the total number of valence electrons. It represents an analogue of the valence shell electron pair (VSEPR) theory for three-dimensional cage molecules.

  7. It is widely known that the skeletal structure of clusters reflects the number of skeletal bonding electron pairs involved, which is called the polyhedral skeletal electron pair theory (PSEPT) or...